API-571 Exam Dumps : Corrosion and Materials Professional

As defined in API RP 571, under Hydrogen Blistering and HIC/SOHIC:

“SOHIC typically manifests as subsurface stepwise cracking, generally oriented perpendicular to the direction of stress.”

“This mechanism initiates below the surface, typically in weld heat-affected zones, and requires metallographic or advanced ultrasonic methods to detect.”

By contrast, SSC, caustic cracking, and amine SCC are primarily surface-initiated, stress-related cracking mechanisms.

Thus, SOHIC is the subsurface mechanism in this list, making option D correct.

According to API RP 571, under the section "4.2.1.2 Brittle Fracture", the following conditions are explicitly identified as most critical for brittle fracture risk:

"Most processes run at elevated temperature, so the main concern is for brittle fracture during startup, shutdown, hydrotest, or other situations where equipment may be exposed to low temperatures."

"Equipment fabricated from materials susceptible to brittle fracture (e.g., carbon steel) is most vulnerable when exposed to low temperatures combined with high stress or pressure."

"A brittle fracture is characterized by a sudden and rapid crack propagation with little or no plastic deformation."

(Reference: API RP 571, Section 4.2.1.2 – Brittle Fracture)

Thus, while other options represent stress events, the main concern specifically noted by the standard is during start-up and shutdown—especially due to cooling and repressurization at low temperatures—making option A the most accurate choice.

Comprehensive and Detailed Explanation From Exact Extract:

Naphthenic Acid Corrosion (NAC) occurs in high-temperature refinery streams (typically 450–750 °F / 230–400 °C) containing organic acids. According to API RP 571, NAC is particularly aggressive toward carbon steels and low-alloy steels, and resistance improves with increasing chromium and molybdenum content, but is best with titanium.

Titanium exhibits exceptional resistance to NAC due to the formation of a stable, protective oxide film that is not attacked by naphthenic acids. API RP 571 identifies titanium as one of the most resistant materials available for severe NAC environments.

Why the other options are less suitable:

Option B (9 Cr-1 Mo steel) has limited resistance and is still susceptible at higher TAN and velocities.

Option C (317 stainless steel) offers improved resistance but can still experience attack under severe NAC conditions.

Option D (321 stainless steel) has lower molybdenum content than 317 SS, making it less resistant.

API RP 571 explicitly notes that titanium provides superior resistance compared to stainless steels and Cr-Mo alloys in NAC service.

Referenced Documents (Study Basis):

API RP 571 – Section on Naphthenic Acid Corrosion

API Corrosion and Materials Selection Study Guide