“Ammonium chloride corrosion is most aggressive when dry salts are exposed to a small amount of free water. This condition allows the formation of a concentrated acidic aqueous solution, which is highly corrosive to carbon steel.”
“The corrosion mechanism is activated especially during startup and shutdown when condensation may occur on salt deposits.”
(Reference: API RP 571, Section 4.3.3.1 – Ammonium Chloride Corrosion)
Hence, while salt deposition begins as temperatures drop, the most aggressive corrosion happens when water is introduced to dry salt, making option D correct.
Question 2
Which of the following damage mechanisms is related to steel hardness?
Options:
A.
Stress-oriented hydrogen-induced cracking
B.
Sulfide stress corrosion cracking
C.
Hydrogen-induced cracking
D.
Hydrogen blistering
Answer:
B
Explanation:
API RP 571 details that:
“Sulfide Stress Cracking (SSC) susceptibility increases significantly with increased hardness of the steel.”
“NACE MR0175/ISO 15156 provides hardness limits for carbon and low-alloy steels to avoid SSC in sour environments. These are typically limited to 22 HRC or 248 Brinell.”
“High hardness promotes crack initiation under tensile stress in sour environments (i.e., containing H₂S).”
(Reference: API RP 571, Section 4.2.2.1 – Sulfide Stress Corrosion Cracking)
While hydrogen-induced cracking (HIC) and blistering are related to hydrogen charging, SSC is the only mechanism directly and critically impacted by hardness, making option B correct.
Question 3
Spheroidization is a change in the microstructure of steels that can occur after exposure to a minimum temperature of:
Options:
A.
650°F (345°C)
B.
700°F (370°C)
C.
850°F (455°C)
D.
1000°F (540°C)
Answer:
A
Explanation:
According to API RP 571 Section 5.3.2.3 (Spheroidization):
“Spheroidization is a microstructural degradation that occurs in carbon steels and low alloy steels when exposed to elevated temperatures for long periods, typically beginning at temperatures as low as 650°F (345°C). It involves the transformation of lamellar pearlite into spherical cementite particles, reducing strength and hardness.”
Thus, Option A (650°F / 345°C) is the minimum threshold temperature for spheroidization to begin.