“Sulfide Stress Cracking (SSC) susceptibility increases significantly with increased hardness of the steel.”
“NACE MR0175/ISO 15156 provides hardness limits for carbon and low-alloy steels to avoid SSC in sour environments. These are typically limited to 22 HRC or 248 Brinell.”
“High hardness promotes crack initiation under tensile stress in sour environments (i.e., containing H₂S).”
(Reference: API RP 571, Section 4.2.2.1 – Sulfide Stress Corrosion Cracking)
While hydrogen-induced cracking (HIC) and blistering are related to hydrogen charging, SSC is the only mechanism directly and critically impacted by hardness, making option B correct.
Question 2
In a naphthenic acid corrosive (NAC) environment, what is the effect of sulfur?
Options:
A.
No effect
B.
Sulfide cracking
C.
Inhibition
D.
Corrosion accelerator
Answer:
C
Explanation:
According to API RP 571 Section 5.1.3.4 (Naphthenic Acid Corrosion - NAC):
“Sulfur can act as an inhibitor to NAC. Where sulfur content in crude is high, a reduction in naphthenic acid corrosion is sometimes observed, especially in certain parts of vacuum and atmospheric units. However, this is not universally reliable, and corrosion can still occur based on local operating conditions and metal temperatures.”
Thus, Option C (Inhibition) is the correct choice, as sulfur can reduce NAC under some conditions.
Question 3
In a wet H2S-type environment, what fluid material will significantly increase the probability of blistering?
Options:
A.
Polythionic acid
B.
Cyanides
C.
Carbonates
D.
Amines
Answer:
B
Explanation:
According to API RP 571 Section 5.1.2.1 (Hydrogen-Induced Cracking) and Publ 939-A, blistering in carbon and low alloy steels exposed to wet H2S environments can be exacerbated by the presence of cyanides. These accelerate hydrogen entry into steel, increasing the chance of hydrogen blistering.
API RP 571 states:
“HIC and blistering are forms of hydrogen damage that occur in wet H2S environments. The presence of cyanides can significantly increase hydrogen entry and the risk of blistering.”
Publ 939-A (Research on Cracking in Wet H2S Service) also notes:
“Cyanides act as catalytic agents in hydrogen charging, which promotes internal pressure build-up and increases blistering.”
Thus, cyanides (Option B) are the most critical in enhancing blistering in H2S environments.